Why Silane Oligomers Improve Coating Adhesion

23 Jul.,2024

 

Silane oligomers have been widely used as adhesion promoters to improve coating adhesion on various substrates. The reason why silane oligomers are effective in improving coating adhesion can be traced to their unique chemical structure and reactivity with both the substrate and the coating resin.

Silane oligomers contain reactive functional groups such as silanol (-Si-OH) and alkoxy (-OR) groups on the same molecule. These functional groups can react with the hydroxyl (-OH) or carboxyl (-COOH) functional groups on the substrate surface through a condensation reaction, forming a covalent bond between the substrate and the silane oligomer. This creates a chemical bridge between the substrate and the coating resin, improving the adhesion between the two.

Moreover, the alkoxy groups on the silane oligomers undergo hydrolysis in the presence of moisture, forming silanol groups that can react with the hydroxyl groups on the coating resins through a similar condensation reaction. This results in the formation of a chemical bond between the coating resin and the silane oligomer, further enhancing the adhesion between the two.

The use of silane oligomers as adhesion promoters has important implications in the coatings industry. It allows for the development of coatings with improved adhesion on a wide range of substrates including metals, plastics, and ceramics. It also enables the possibility of using a wider range of coating resins with varying solubilities and viscosities, as silane oligomers can bridge the adhesion gap between different materials.

In conclusion, the unique chemical structure of silane oligomers and their ability to react with both the substrate and the coating resin through condensation reactions, make them effective adhesion promoters for coatings. Their use has important implications in the coatings industry, improving the adhesion properties of coatings and enabling the development of coatings on a wider range of substrates.

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