How is hydrogen peroxide manufactured?

16 Jul.,2024

 

Hydrogen peroxide is a chemical compound famously known for its various applications in medicine, cleaning, and even rocketry. This powerful oxidizer is especially popular as a disinfectant and bleaching agent. But if we take a closer look at the manufacturing process, what we would find would be quite surprising and fascinating.

So how is hydrogen peroxide manufactured?

The manufacturing of hydrogen peroxide involves various steps in which it is produced in large quantities with purity levels that meet the required industrial standards. The process employs a mix of technology, chemistry, and thermodynamics, which I will explain the step-by-step process in the following paragraphs.

Step 1: Anthraquinone Production – The Preparatory Stage.

The first stage is the production of anthraquinone, the precursor chemical that is necessary in the manufacturing process. This substance is produced by a chemical reaction involving benzene and phthalic acid. The resulting chemical is then oxidized with a range of acids and catalysts to produce anthraquinone.

Step 2: Hydrogenation.

In the second step, anthraquinone is then hydrogenated, making it soluble in alcohol. The catalytic hydrogenation process is carried out in the presence of palladium catalyst and a hydrogen source. The reaction produces anthrahydroquinone and is carried out at relatively high pressures and temperatures.

Step 3: Oxidation.

In the next step, the anthrahydroquinone is oxidized to produce hydrogen peroxide. This reaction is carried out with hydrogen, anthraquinone and oxygen that is catalyzed with numerous substances, the most common being silver or palladium. By-product of the reaction is water.

The stability of hydrogen peroxide is limited to a maximum of 60% concentration in the presence of trace amounts of anthraquinone. However, with the complete removal of anthraquinone by filtering, it is possible to achieve higher concentrations of above 90%.

Step 4: Concentration.

The next stage is the concentration of the hydrogen peroxide. A concentrator is used to evaporate water separating and retaining the purified hydrogen peroxide. The concentration is then continued until desired purity and concentration are achieved.

Step 5: Stabilization.

In the last step, stabilizers are added to keep the hydrogen peroxide stable and prevent its degradation in storage. Acids such as phosphoric and sodium Stannate are added to minimize decomposition of the hydrogen peroxide solutions.

Industrial production of hydrogen peroxide typically runs continuously, 24 hours a day, and seven days a week.

In the early manufacturing process, hydrogen peroxide was produced using the electrolysis of sulfuric acid. This method was very dangerous and resulted in a low yield of hydrogen peroxide.

The science behind the production process has evolved and improved significantly. The method used today, called the anthraquinone process, has improved the purity and yield of the finished product while reducing the risk of burning incidences.

In terms of the environmental impact, the production of hydrogen peroxide has minimal impact as there are no hazardous waste products produced, and the entire process is executed with relative safety.

Conclusion.

In summary, hydrogen peroxide is an important oxidant and a widely used chemical compound. Its widespread applications in industries, medicine, and skincare products have made it a significant chemical.

The anthraquinone process is the most widely used method in the production of hydrogen peroxide. It handles the production of hydrogen peroxide on an industrial scale, ensuring that the required levels of purity are achieved while ensuring sustainability and safety.

As more applications are discovered for hydrogen peroxide, the significance of its production process will continue to grow, and its importance in the market will remain at the forefront of chemical production.

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